How much do you want to spend?
If you go for a Raspberry Pi have a look at Terrapi cases as well the obvious Argon ones.
Another option would be a Zimbaboard. It is more expensive but it has dual SATA connector (you need to buy a Y cable with the Zimbaboard) and there are 3D print designs to create a single unit, e.g. https://www.printables.com/model/224057-zimaboard-dual-hdd-stand.
I’m not sure about PoE and a NAS. Will a PoE HAT or similar provide enough power for the board and the drives?
Have you ensured that your setup will pass email authentication processes?
It has been a long time since email from random hosts is accepted for forwarding or delivery. This Wikipedia may help https://en.wikipedia.org/wiki/Email_authentication